The study explores the adoption of an electronic government (e-government) system called electronic district (e-District) system in context of India. The study validates the decomposed theory of planned behaviour (DTPB) to understand the impact of its factors on the potential adopter’s intention to adopt this system. The proposed research model is validated using the data collected from 304 respondents from a state called Bihar of India where this e-government was supposed to be implemented. The data is analysed through regression analysis technique. The empirical findings of the proposed research model indicated the significant relationships of all proposed hypotheses. The study also provides its limitations, future research directions, and implications for theory and practice toward the end.