Requirements specification should not be concerned only with the software specification, but should also be able to integrate with the organizational models describing the environment in which the system will function. Agent–oriented conceptual modeling notations such as i* represents an interesting approach for modeling early phase requirements which includes organizational contexts, stakeholder intentions and rationale. Business Process Modeling notations such as BPMN are used to effectively conceptualize and communicate important process characteristics to relevant stakeholders. On the other hand, Unified Modeling Language (UML) is suitable for later phases of requirement capture which usually focus on completeness, consistency, and automated verification of functional requirements for the new system. In this paper, we illustrate the use of a methodology that facilitate and support the combined use of notation for modeling requirement engineering process in a synergistic fashion in a complex project for a large government Department. The notations we used were i*, BPMN and UML Use Case.