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The purpose of this paper is to provide new evidence on the relationship between industrial migration and “Internet+” economy diffusion. For this purpose we conduct the research by Industrial Structure Migration Assessment Model as well as empirical data during the period from 2010 to 2015. On the basis of empirical tests of Chengdu, Chongqing, Xi’an and Kunming, we focus on the “Internet+” economy development of growth poles in Diamond Economic Circle. We find that industrial structure in these regions has shown an obvious trend of advanced, inertia and cooperative, which improves the capacity of e-readiness and lays favorable foundation for “Internet+” economy diffusion for Diamond Economic Circle. Polices for developing “Internet+” economy in Diamond Economic Circle are suggested at last.