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As a new business model in the business society, E-commerce takes an important place in now and future business activities Third party logistics is a very successful ways to implement the logistics concerned with E-commerce. In developing the cooperation and alliances relationship between the third party provider and the companies trust plays an important role. The article described the role of trust in developing relationships between the third party logistics providers and the e-commerce companies. A four dimension of trust model is provided and the proposal methodology is given.